8. a second-order reaction has a half-life of 18 s when the initial concentration of reactant is 0.71 m. calculate the rate constant for this reaction

Answers

Answer 1

The rates are constant for this reaction 0.0782 M⁻¹s⁻¹. Second-order reactions are those in which the total of the exponents in the appropriate rate law of the chemical reaction equals two.

Second-order reactions are chemical processes that depend on either the concentrations of two first-order reactants or the concentration of one second-order reactant, according to the rate law equations provided below. A chemical reaction's half-life is the length of time it takes for half of the reactant to move through the reaction.

Second-order kinetics can be used to explain a variety of significant biological processes, including the creation of double-stranded DNA from two complementary strands. The total of the exponents in the rate law is equal to two in a second-order reaction. In this section, the two most typical types of second-order reactions will be thoroughly covered.

The differential (derivative) rate equation and the integrated rate equation are used to explain how the rate of a second-order reaction varies with the concentration of reactants or products. The integrated rate equation demonstrates how the concentration of species varies over time, whereas the differential rate law demonstrates how the reaction's rate changes over time.

Second order reaction for calculating rate constant is

t1/2 = 1/KCAO

Half-Life period = 18 s

Initial Concentration of reactant = 0.71M

18s = 1/K(0.71M)

K = 0.0782 M⁻¹s⁻¹

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Related Questions

Based on what you have discovered, which of the following conditions would lead to formation of clouds?
1. Moist air moves up as it encounters a mountain range.
2. High pressure is moving into an area.
3. The air over a large parking lot is warmer in the afternoon than the surrounding park is.
4. The horse latitudes the areas of sinking air.
5. Low pressure moves into your area
Answer

Answers

1-Moist air moves up as it encounters a mountain range: This condition can lead to the formation of clouds because as moist air rises, it cools, and the water vapor in the air condenses into liquid water droplets or ice crystals, which can form clouds.

2-High pressure is moving into an area: High-pressure systems are associated with clear and sunny weather, so this condition is less likely to lead to the formation of clouds.

3-The air over a large parking lot is warmer in the afternoon than the surrounding park is: This condition can lead to the formation of cumulus clouds as the warm air rises and cools, and water vapor condenses into visible clouds.

4-The horse latitudes are the areas of sinking air: This condition is associated with clear and dry weather, so it is less likely to lead to the formation of clouds.

5-Low pressure moves into your area: This condition can lead to the formation of clouds as the rising warm, moist air cools and condenses into clouds.

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you have 20 gr of phosphorus that decays 5% per day. how long will it take for half the amount to decay?

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The decay of phosphorus can be modeled using exponential decay, which is given by the equation:

N(t) = N0 × e^(-kt)

where N(t) is the amount of phosphorus remaining at time t, N0 is the initial amount of phosphorus (20 g in this case), k is the decay constant, and e is the base of the natural logarithm (approximately equal to 2.718).

The percentage decay per day is given as 5%, which means that the decay constant k can be calculated as follows:

k = ln(1 - 0.05)/(-1 day) ≈ 0.0513 day^(-1)

To find the time it takes for half the amount of phosphorus to decay, we can set N(t) equal to N0/2 and solve for t:

N(t) = N0/2 = N0 × e^(-kt)

e^(-kt) = 1/2

Taking the natural logarithm of both sides, we get:

-ln(2) = -kt

Solving for t, we get:

t = ln(2)/k ≈ 13.5 days

Therefore, it will take about 13.5 days for half of the initial amount of phosphorus (10 g) to decay.

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how is an unknown oxidation state of an element within a compound determined

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Explanation:

You assign oxidation numbers to the elements in a compound by using the Rules for Oxidation Numbers.

The oxidation number of a free element is always 0.

The oxidation number of a monatomic ion equals the charge of the ion.

The oxidation number of H is +1, but it is -1 in when combined with less electronegative elements.

The oxidation number of O in compounds is usually -2, but it is -1 in peroxides.

The oxidation number of a Group 1 element in a compound is +1.

The oxidation number of a Group 2 element in a compound is +2.

The oxidation number of a Group 17 element in a binary compound is -1.

The sum of the oxidation numbers of all of the atoms in a neutral compound is 0.

The sum of the oxidation numbers in a polyatomic ion is equal to the charge of the ion.

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if 1g of magnesium and 1g of oxygen reacted, what will be left in the reaction vessel?

a)MgO only
b)MgO and Mg only
c)MgO and O2 only
d) MgO, Mg and O2

Answers

The answer is (a) MgO only, as all of the magnesium and oxygen react completely to form magnesium oxide, and there would be no unreacted magnesium or oxygen left in the reaction vessel.

What is Limiting Reagent?

The limiting reagent can be determined by comparing the mole ratios of the reactants and the coefficients in the balanced chemical equation for the reaction. The reactant that produces the least amount of product based on the stoichiometry of the balanced equation is the limiting reagent.

If 1g of magnesium (Mg) and 1g of oxygen (O2) reacted, they would combine to form magnesium oxide (MgO) according to the following chemical equation:

2Mg + O2 -> 2MgO

The molar mass of magnesium is 24.31 g/mol, while the molar mass of oxygen is 32.00 g/mol. Therefore, 1g of magnesium is equivalent to 0.041 mol, and 1g of oxygen is equivalent to 0.03125 mol.

According to the balanced equation, 2 moles of magnesium react with 1 mole of oxygen to form 2 moles of magnesium oxide. Thus, the limiting reactant in this reaction is oxygen because only 0.03125 mol of oxygen is available, whereas 0.082 mol of magnesium is available.

Using the limiting reactant, we can calculate the theoretical yield of magnesium oxide:

0.03125 mol O2 x (2 mol MgO / 1 mol O2) x (40.31 g MgO / 1 mol MgO) = 2.5 g MgO

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an aqueous solution of ca(oh)2 with a ph of 14.235 is prepared in a 500.00 ml volumetric flask by adding 91.138 ml of a ca(oh)2 stock solution. what is the concentration of the ca(oh)2 stock solution (units are m)?

Answers

The concentration of the Ca(OH)₂ stock solution is 0.00511 M.

The pH of an aqueous solution of Ca(OH)₂ can be calculated using the following equation,

pH = 14 - log([Ca(OH)₂])

where [Ca(OH)₂] is the concentration of Ca(OH)₂ in moles per liter (M).

Since the solution has a pH of 14.235, we can plug this value into the equation and solve for [Ca(OH)₂]:

14.235 = 14 - log([Ca(OH)₂])

log([Ca(OH)₂]) = 14 - 14.235 = -0.235

[Ca(OH)₂] = 10^(-0.235) = 0.00513 M

The Ca(OH)₂ stock solution was diluted to a final volume of 500.00 ml by adding 91.138 ml of the stock solution to a volumetric flask and filling up to the mark with water. Therefore, the number of moles of Ca(OH)₂ in the stock solution can be calculated as:

moles of Ca(OH)₂ = concentration × volume = [Ca(OH)₂] × (91.138/1000) = 0.000467 moles

The stock solution was diluted to a final volume of 500.00 ml, so the final concentration of the Ca(OH)₂ solution is:

final concentration = moles / volume = 0.000467 moles / 0.500 L = 0.000934 M

Therefore, the concentration of the Ca(OH)₂ stock solution is:

concentration = final concentration × (final volume / initial volume) = 0.000934 M × (500.00 ml / 91.138 ml) = 0.00511 M

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What is the vapor pressure of water at 75 °C? mmHg (whole number)

What is the vapor pressure of bromine at 300 K? mmHg (whole number)

At what temperature is the vapor pressure of mercury 500 mmHg? °C (whole number)

What is the vapor pressure of diether ether at the normal freezing temperature of water? mmHg (whole number)

At what temperature will ethanol boil when at 50 mmHg? °C (whole number)

What is the normal boiling point pressure for water in kPa? kPa (exact number)

What is the normal boiling point pressure for water in mmHg? mmHg (exact number)

What is the normal boiling point temperature in Celsius of n-Octane? °C (whole number)

What is the normal boiling point temperature in Kelvin of Ethylene glycol? K (whole number)

At which temperature would ethylene glycol boil when the atmospheric pressure is 0.20 atm? °C (Whole number)

Answers

Answer: All the answers are given below.

Explanation:

The vapor pressure of water at 75°C is approximately 293 mmHg (whole number).

The vapor pressure of bromine at 300 K is approximately 240 mmHg (whole number).

The boiling point of mercury is 357°C at atmospheric pressure (760 mmHg), and the vapor pressure of mercury is 500 mmHg at a higher temperature than this. Therefore, the temperature at which the vapor pressure of mercury is 500 mmHg is greater than 357°C.

Diethyl ether's normal boiling point is 34.6°C, which is above the freezing temperature of water (0°C). At 0°C, the vapor pressure of diethyl ether is approximately 5.5 mmHg (whole number).

At a pressure of 50 mmHg, ethanol will boil at approximately 64°C (whole number).

The normal boiling point pressure for water is 101.3 kPa (exact number) at a temperature of 100°C.

The normal boiling point pressure for water is 760 mmHg (exact number) at a temperature of 100°C.

The normal boiling point temperature in Celsius of n-Octane is approximately 126°C (whole number).

The normal boiling point temperature in Kelvin of ethylene glycol is approximately 471 K (whole number).

To find the boiling point of ethylene glycol at a pressure of 0.20 atm, you can use the Clausius-Clapeyron equation. However, the equation requires knowing the vapor pressure of ethylene glycol at a known temperature. Without this information, it is not possible to calculate the boiling point.

the dissolution of ammonium nitrate occurs spontaneously in water. as nh4no3 dissolves, the temperature of the water decreases. what are the signs of the changes of h, s, and g for this process? a. incrementh < 0, increments > 0, incrementg < 0 b. incrementh > 0, increments < 0, incrementg > 0 c. incrementh > 0, increments > 0, incrementg < 0 d. incrementh < 0, increments > 0, incrementg < 0 e. incrementh < 0, increments < 0, incrementg < 0

Answers

The correct option is d. increment H < 0, incrementS > 0, incrementG < 0.

When NH4NO3 dissolves, the temperature of the water decreases. What are the signs of the changes of H, S, and G for this process?The sign of changes in enthalpy (ΔH) for the dissolution of ammonium nitrate (NH4NO3) in water is negative.

It means that the process releases heat, and it is exothermic. The dissolution of NH4NO3 in water is a spontaneous process and hence its entropy change (ΔS) is positive.

Therefore, the dissolution of NH4NO3 in water leads to an increase in the entropy of the system. Since the dissolution process is exothermic, the change in Gibbs free energy (ΔG) is negative, indicating that it is spontaneous.

Thus, the signs of changes in H, S, and G for the dissolution of ammonium nitrate in water are: ΔH < 0 When NHd ΔG < 0.

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why will the conjugate base of a weak acid affect ph? select the correct answer below: it will react with hydroxide it will react with water it will react with hydronium none of the above

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The conjugate base of a weak acid affect ph because it will react with water. Option b is correct.

When a weak acid, HA, donates a proton to water, it forms its conjugate base, A-. This reaction is an equilibrium process, and at equilibrium, a certain percentage of the weak acid will have dissociated into its conjugate base and hydronium ions.

The conjugate base A- can then react with water to regenerate the weak acid and hydroxide ions. This reaction shifts the equilibrium to the left, decreasing the concentration of hydronium ions and increasing the concentration of hydroxide ions, which increases the pH of the solution.

Therefore, the presence of the conjugate base of a weak acid affects the pH of a solution by shifting the equilibrium between the weak acid and its conjugate base towards the acid side, decreasing the concentration of hydronium ions and increasing the concentration of hydroxide ions. Hence option b is correct.

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Which term is used to describe why we can smell air freshener across the room shortly after it has been sprayed? A. elastic collisions B. osmosis C. diffusion D. temperature​

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The diffusion term is used to describe why we can smell air freshener across the room shortly after it has been sprayed, hence option C is correct.

When you spray the air freshener, the matter goes from a high concentration region to a low concentration area that is far away from the spraying location. Diffusion is the term used to describe this material movement.

Diffusion is the overall net movement of something from a higher concentration to a lower concentration.

The term "diffusion" is used to explain why we can smell air freshener across the room quickly after it has been applied.

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another metal phosphate is cobalt(iii) phosphate. it will behave similar to calcium phosphate in an acid solution, and will form an equilibrium between reactants and products. what is the net ionic equation including phases for copo4(s) dissolving in h3o (aq) ?

Answers

The net ionic equation for the dissolution of solid cobalt(III) phosphate, CoPO₄(s), in an acid solution can be written as; CoPO₄(s) + 3H₃O⁺(aq) ↔ Co₃⁺(aq) + H₂PO₄⁻(aq) + 3H₂O(l)

In this reaction, CoPO₄(s) reacts with hydronium ions, H₃O⁺(aq), to form cobalt(III) ions, Co₃⁺(aq), and hydrogen phosphate ions, H₂PO₄⁻(aq), along with water molecules, H₂O(l). The hydrogen phosphate ion, H₂PO₄⁻, is the product of the reaction and is formed by the reaction of H₃O⁺ with PO₄³⁻ in CoPO₄(s), which acts as a weak acid.

The net ionic equation only shows the species that are directly involved in the chemical reaction, so the spectator ions, such as counterions, are omitted. In this case, the counterion for CoPO₄ is not included in the net ionic equation since it does not participate in the reaction.

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which factor, the change in enthalpy, or the change in entropy, provides the principal driving force for this reaction.

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The enthalpy is the principal driving force because it is a large enough negative value to ensure the free energy is negative, making the reaction spontaneous. Hence, option A is correct.

In order to determine the driving force for a reaction, we look at the Gibbs free energy change (ΔG). The Gibbs free energy is given by the equation:

ΔG = ΔH - TΔS

where ΔH is the enthalpy change, T is the temperature in Kelvin, and ΔS is the entropy change. If ΔG is negative, the reaction is spontaneous, meaning that it will occur without any external input of energy. If ΔG is positive, the reaction is nonspontaneous and will only occur with an input of energy.

Assuming that ΔS° is also negative, option A is the best choice, The enthalpy is the principal driving force because it is a large enough negative value to ensure the free energy is negative, making the reaction spontaneous. This option assumes that ΔS° is negative, which would result in a negative ΔG value and a spontaneous reaction.

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--The complete question is, Consider the reaction CO2(g) + 2NH3(g) à CO(NH2)2(s) + H2O(l) ΔH° 298K = -134kJ b. Which factor, the change in enthalpy, ΔH°, or the change in entropy, ΔS° provides the principle driving force for the reaction at 298K? Explain.

A) The enthalpy is the principal driving force because it is a large enough negative value to ensure the free energy is negative, making the reaction spontaneous

B) The enthalpy is the principal driving force because it is a large enough negative value to ensure the free energy is positive, making the reaction nonspontaneous

C) The entropy is the principal driving force, because it is a large enough negative value to ensure the free energy is negative making the reaction spontaneous

D) The entropy is the principal driving force, because it is a large enough negative value to ensure the free energy is positive making the reaction nonspontaneous--

you observe a molecule that has a central carbon with an attached hydrogen atom, carboxyl group, and amino group. the molecule is a(n):

Answers

They  perform a wide range of functions in the body such as catalyzing reactions, transporting molecules, and providing structural support to cells and tissues.

When answering questions on the platform Brainly, the following guidelines should be followed:- Always be factually accurate, professional, and friendly- Be concise and do not provide extraneous amounts of detail-

Ignore any typos or irrelevant parts of the question- Use the relevant terms in your answer as provided in the student question.The molecule that has a central carbon with an attached hydrogen atom, carboxyl group, and amino group is an amino acid.

Amino acids are the building blocks of proteins. They contain an amino group (-NH2), a carboxyl group (-COOH), and a side chain (-R) attached to the central carbon atom. Some amino acids have additional functional groups such as hydroxyl (-OH), sulfur (-SH), or a ring structure.

Amino acids are the building blocks of proteins. Amino acids can form peptide bonds with other amino acids to form proteins. Proteins are the basic functional and structural units of life.

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how does the strength of the attraction between water molecules and sodium and chloride ions compare

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The strength of the attraction between water molecules and sodium and chloride ions is stronger compared to the attraction between water molecules themselves. This is due to the ion-dipole interaction between charged ions and polar water molecules.

The strength of the attraction between water molecules and sodium and chloride ions is generally stronger than the attraction between water molecules themselves. This is due to the following reasons:
1. Water molecules are polar, which means they have a partially positive charge on the hydrogen atoms and a partially negative charge on the oxygen atom.
2. Sodium and chloride ions are charged particles, with sodium ions having a positive charge and chloride ions having a negative charge.
3. When water molecules come into contact with sodium and chloride ions, the positive charge on the sodium ions attracts the negatively charged oxygen atoms in water molecules, and the negative charge on the chloride ions attracts the positively charged hydrogen atoms in water molecules.
4. This attraction between charged ions and polar water molecules is called ion-dipole interaction, which is stronger than the hydrogen bonding between water molecules.

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we learned that k is adsorbed to negatively charged soil colloids by electrostatic attraction to three types of exchange sites or binding positions. which binding position is readily available to the soil solution?

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We learned that k is adsorbed to negatively charged soil colloids by electrostatic attraction to three types of exchange sites or binding positions. The cation exchange sites are the most readily available to the soil solution.

The binding position that is readily available to the soil solution is the cation exchange sites. This is because the negatively charged soil colloids attract positively charged ions, known as cations, through electrostatic attraction. These cations are then exchanged with other cations in the soil solution, leading to the term "cation exchange sites."

The other two types of exchange sites are the anion exchange sites, which attract negatively charged ions, known as anions, and the inner sphere binding sites, which involve a direct bond between the metal ion and the soil colloid surface. However, the cation exchange sites are the most readily available to the soil solution.

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Which description best reflects the strategy "adopt an identity"?

People who enjoy traveling frequent a restaurant that offers an "around the world" tasting menu.
People who love the Star Wars™ films flock to the opening of the new Star Wars™ theme park.
People who love the television series Game of Thrones™ book a tour of its shooting locations.
People who wear Nike™ sneakers "just do it" when it comes to challenging physical activity.

Answers

The description that best reflects the strategy "adopt an identity" is: People who wear Nike™ sneakers "just do it" when it comes to challenging physical activity.

"Adopt an identity" is a marketing strategy that appeals to people's sense of self-identity and the desire to express themselves through the brands and products they consume. The Nike™ slogan "just do it" encourages people to identify themselves as athletes or fitness enthusiasts and to associate that identity with the brand. By adopting the identity of a Nike™ wearer, people are not only buying a product but also adopting a lifestyle and a set of values that the brand represents. This strategy is effective because it creates an emotional connection between the consumer and the brand, which can lead to brand loyalty and repeat purchases.

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how the solubility product can be used to predict if a precipiate will form when two aqeuous solutions are mixed

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The solubility product (Ksp) can be used to predict whether a precipitate will form when two aqueous solutions are mixed by comparing the ion product (Q) with the Ksp value.

When two solutions are mixed, the ions present in each solution may combine to form a new compound that has a low solubility, resulting in the formation of a precipitate. The solubility product constant (Ksp) is a measure of the maximum amount of a compound that can dissolve in water at equilibrium.

If the ion product (Q) of the solution is less than the Ksp value, then the solution is unsaturated and no precipitate will form. However, if Q is greater than Ksp, then the solution is supersaturated, and a precipitate will form until the concentration of ions in the solution reaches the solubility limit.

In other words, if Q>Ksp, then the solution is supersaturated, and precipitation will occur until Q=Ksp. If Q<Ksp, the solution is unsaturated, and no precipitation will occur. If Q=Ksp, the solution is at saturation and no further precipitation will occur.

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Calculate the volume of oxygen produced at 298K and 100 kPa by the decomposition of 30 cm3 of 0.1 mol dm_3 H2O2.

Answers

The balanced chemical equation for the decomposition of hydrogen peroxide is:

2 H2O2 (aq) → 2 H2O (l) + O2 (g)

From this equation, we can see that for every 2 moles of hydrogen peroxide that decompose, 1 mole of oxygen is produced.

We can start by calculating the number of moles of H2O2 that are present in 30 cm3 of 0.1 mol dm-3 H2O2:

30 cm3 = 30/1000 dm3 = 0.03 dm3
number of moles of H2O2 = concentration × volume = 0.1 mol dm-3 × 0.03 dm3 = 0.003 moles

Since 2 moles of H2O2 decompose to produce 1 mole of O2, we can calculate the number of moles of O2 produced:

number of moles of O2 produced = 0.003 moles H2O2 × (1 mole O2 / 2 moles H2O2) = 0.0015 moles O2

Now we can use the ideal gas law to calculate the volume of O2 produced:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant (0.0821 L atm mol-1 K-1), and T is the temperature in Kelvin.

We can rearrange this equation to solve for V:

V = nRT / P

Plugging in the values, we get:

V = (0.0015 mol)(0.0821 L atm mol-1 K-1)(298 K) / (100 kPa)(101.325 kPa atm-1)
V = 0.0377 L

Therefore, the volume of oxygen produced at 298K and 100 kPa by the decomposition of 30 cm3 of 0.1 mol dm-3 H2O2 is 0.0377 L.

a current of 0.550 a passed for 29.0 min through a cuso4 solution. calculate the amount of copper deposited.

Answers

The amount of copper deposited in the CuSO₄ solution is 0.315 grams.

To calculate the amount of copper deposited in this case, we can use Faraday's laws of electrolysis. First, we need to convert the time given from minutes to seconds, and find the total charge passed.

Time (t) = 29.0 minutes × 60 seconds/minute = 1740 seconds

Current (I) = 0.550 A

Total charge (Q) = Current × Time = 0.550 A × 1740 s = 957 A·s

Now, we need to find the moles of electrons transferred using Faraday's constant (F = 96,485 C/mol).

Moles of electrons (n) = Total charge / Faraday's constant = 957 A·s / 96,485 C/mol = 0.00992 mol

The reaction for copper deposition is: Cu²⁺ + 2e⁻ → Cu

From the reaction, we can see that 2 moles of electrons deposit 1 mole of copper. So, we need to determine the moles of copper deposited.

Moles of Cu = Moles of electrons / 2 = 0.00992 mol / 2 = 0.00496 mol

Finally, we calculate the mass of copper deposited using its molar mass (M = 63.55 g/mol).

Mass of Cu = Moles of Cu × Molar mass = 0.00496 mol × 63.55 g/mol = 0.315

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if benzaldehyde was used instead of benzophenone, what would be the expected product? select one: diphenylmethanol benzene benzoic acid triphenylmethanol

Answers

Answer:

a. diphenylmethanol

Explanation:

As benzaldehyde is used instead of benzophenone, the expected product is Diphenylmethanol.

Benzophenone is a molecule of the ketone type that is made up of two phenyl groups that are bonded to a carbonyl group. In polar solvents, it is a crystalline substance that is almost white, odorless, and has a faintly sweet taste. It is commonly used as a UV light stabilizer for various plastics and as a chemical intermediate in the manufacture of pharmaceuticals, fragrances, and dyes. Diphenylmethanol is an organic compound that belongs to the class of aromatic alcohol. It is a white crystalline substance that has a sweet, floral scent. It is produced by combining benzaldehyde with the Grignard reagent. The reaction will lead to the formation of Diphenylmethanol. Therefore, if benzaldehyde was used instead of benzophenone, the expected product would be Diphenylmethanol.

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The Pacific Plate moves to the northwest at an average rate of 10 cm per year. Hawaii is in the middle of the Pacific Plate, 6,600 kilometers southeast of Japan, which is on the edge of several adjacent plates. If the Pacific Plate continues to move at the same rate and in the same direction, when will Hawaii collide with Japan? Show your work.

Answers

To solve this problem, we first need to convert the distance between Hawaii and Japan from kilometers to centimeters, which is the unit used for the plate movement rate.

6600 kilometers is equal to 6,600,000 centimeters (1 kilometer = 100,000 centimeters).

Next, we can use the formula:

distance = rate × time

to calculate the time it will take for Hawaii to collide with Japan.

Let t be the time in years. The distance traveled by the Pacific Plate in t years is:

distance = rate × time = 10 cm/year × t

So, the distance Hawaii moves in t years is 10 cm/year × t.

At the same time, Japan moves in the opposite direction at the rate of the adjacent plate, but we don't know this value. We can assume that Japan is stationary relative to the adjacent plate, so the distance it moves is zero.

The total distance between Hawaii and Japan is decreasing at a rate of 10 cm/year:

rate of decrease = 10 cm/year

So we can set up the following equation:

6,600,000 cm - 10 cm/year × t = 0

Solving for t, we get:

t = 6,600,000 cm / (10 cm/year) = 660,000 years

Therefore, it will take 660,000 years for Hawaii to collide with Japan, assuming that the Pacific Plate continues to move at the same rate and in the same direction.

The diagram shows the potential energy changes for a reaction pathway.
Potential Energy
B
Reaction Pathway
Part 1: Describe how you can determine the total change in enthalpy and activation energy from the diagram, and if each is positive or negative.
Part 2: Describe how the curve will look if the reaction was exothermic. Be sure to mention changes in the potential energies of the reactants and products and the sign
changes of the enthalpy.

Answers

Answer:

Part 1:

To determine the total change in enthalpy (ΔH) from the diagram, we need to look at the difference between the potential energy of the products and the potential energy of the reactants. In this diagram, the potential energy of the products (point B) is higher than the potential energy of the reactants (point A), so ΔH is positive.

To determine the activation energy (Ea), we need to look at the difference between the potential energy of the reactants and the highest point on the curve, also known as the transition state (point C). In this diagram, the potential energy of the reactants (point A) is lower than the potential energy of the transition state (point C), so Ea is positive.

Part 2:

If the reaction was exothermic, the potential energy of the products would be lower than the potential energy of the reactants. This means that the curve would be inverted, with the potential energy decreasing as the reaction proceeds. The potential energy of the reactants would be higher than the potential energy of the products.

The enthalpy change (ΔH) for an exothermic reaction would be negative, as energy would be released during the reaction. The activation energy (Ea) would still be positive, as the reactants would still need to absorb energy to reach the transition state. However, the height of the curve would be lower for an exothermic reaction, indicating a lower activation energy.

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1 point
What volume of concentrated 1.5M is required to prepare 25 mL of a 7.0M solution?
*Answer in liters
Type your answer...
1 point

Answers

The volume of the concentrated 1.5 M solution required to prepare 25 mL of a 7.0 M solution is 0.117 L or 117 mL.

To solve the problem, we use the formula M1V1 = M2V2, which relates the initial concentration and volume of the concentrated solution (M1V1) to the final concentration and volume of the diluted solution (M2V2). In this case, we are given the final concentration (M2 = 7.0 M), the final volume (V2 = 25 mL), and the initial concentration (M1 = 1.5 M), so we can solve for the initial volume (V1) of the concentrated solution that we need to use.

We rearrange the formula to solve for V1, which gives us V1 = (M2 x V2) / M1. We substitute the given values into this equation, and we get V1 = (7.0 M x 0.025 L) / 1.5 M = 0.117 L or 117 mL.

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the cis ketone a is isomerized to the trans ketone b with aqueous naoh. a similar isomerization reaction does not occur with the cis ketone c. explain this difference in reactivity. be sure to answer all parts.

Answers

When cis-ketone a is isomerized to trans ketone b with aqueous NaOH, it is because cis-ketones exist as a pair of rotamers that interconvert slowly at room temperature.

The two rotamers have different dipole moments, which makes them distinguishable from each other. This isomerization reaction does not occur with the cis-ketone c because there is no appreciable barrier to interconversion between the two rotamers. Thus, the two cis-ketone isomers are indistinguishable from each other in terms of dipole moment, making the reaction of the cis-ketone c unresponsive to the NaOH solution.

What is a cis-ketone, A ketone in which the carbonyl group is adjacent to an alkene group is referred to as a cis-ketone. The cis-ketone has a higher dipole moment than the trans-ketone due to the presence of the alkene group. As a result, the cis-ketone has a greater polarity than the trans-ketone, which has a lower dipole moment.

Trans and cis isomerismIn cis and trans isomerism, the isomers are chemically the same but differ in the way atoms are arranged in space. The terms "cis" and "trans" are used to describe this configuration in organic chemistry. In a molecule, cis isomers are those in which two substituents are on the same side of a bond, while trans isomers are those in which two substituents are on opposite sides of a bond.

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a vinegar sample requires 41.30 ml of a 0.1042 m naoh solution to reach the phenolphthalein endpoint. calculate the moles of acetic acid present in the vinegar sample.

Answers

The moles of acetic acid in the vinegar sample during the addition of NaOH is found to be 4.30 moles.

It is provided that vinegar sample is titrated in presence of phenolphthalein indicator to show the end point of the titration with 41.30 ml of 0.1042M NaOH.

The reaction goes like this,

CH₃COOH + NaOH → CH₃COONa + H₂O

So, as we can see, the moles of acetic acid are equal to the moles of NaOH in the solution.

So, the moles of NaOH are given as,

Moles = Molarity x volume

Moles = 0.1042 x 41.30

Moles = 4.30

So, the moles of acetic acid in the vinegar solution will be equal to the 4.30 moles.

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Can someone fill out the first table for me or tell me what needs to be written in the table

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Answer:

In Table 6.1, the initial solutions of each metal are provided: Cu(NO3)2, Fe(NO3)3, and Zn(NO3)2. The table is asking for the results of the oxidation-reduction reactions that occur when these metals are reacted with each other.

In Table 6.2, the metals (Cu, Fe, Zn) are listed, and the table is asking whether each metal was oxidized or not, and what oxidizing agent(s) were involved in the reaction.

1. Zn is the most reactive metal because it readily undergoes oxidation when in contact with other metals. This is known as the activity series of metals.

2. The order of increasing reactivity is Cu, Fe, Zn.

3. The chemical equations for each single replacement reaction are:

Cu + Zn(NO3)2 → Cu(NO3)2 + Zn

Fe + Cu(NO3)2 → Fe(NO3)2 + Cu

Zn + Fe(NO3)3 → Zn(NO3)2 + Fe

4. Fe was reduced, and Cu and Zn acted as reducing agents.

Explanation:

consider a cell that is composed of tin metal in contact with a solution of tin (ii) sulfate, snso4, and zinc metal in a solution of zinc nitrate, zn(no3)2. answer the following questions, the reduction half reactions are provided. a) which is the reduction reaction? b) which is the oxidation reaction? c) write the overall reaction d) calculate the voltage for this cell. e) label the following on the diagram o zinc electrode o tin electrode o zinc solution o tin (ii) solution o anode o cathode o salt bridge (nano3) o voltage o draw an arrow to show the direction that the electrons travel o write the ions present in the salt bridge o use arrows to indicate the direction that the ions in the salt bridge will travel f) what will happen to the mass of each electrode as the reaction proceeds?

Answers

a) The reduction reaction is the reaction that occurs at the zinc electrode, which is Zn²⁺(aq) + 2e⁻ → Zn(s).

b) The oxidation reaction is the reaction that occurs at the tin electrode, which is Sn(s) → Sn²⁺(aq) + 2e⁻.

c) The overall reaction is: Sn(s) + Zn²⁺(aq) → Sn²⁺(aq) + Zn(s).

d) The overall voltage for the cell is the difference between these two potentials is -0.62 V.

e) Zn electrode | Zn(NO₃)₂ || SnSO₄ | Sn electrode

f) As the reaction proceeds, the mass of the tin electrode will decrease as tin atoms are oxidized to form Sn²⁺ ions.

To calculate the voltage for this cell, we need to use the standard reduction potentials for the half reactions. The standard reduction potential for the reduction reaction is -0.76 V, and the standard reduction potential for the oxidation reaction is -0.14 V. The overall voltage for the cell is the difference between these two potentials: Ecell = Ered - Eox = (-0.76 V) - (-0.14 V) = -0.62 V.

In a galvanic cell, the reduction reaction occurs at the cathode, while the oxidation reaction occurs at the anode. In this case, the zinc electrode is the cathode, where Zn²⁺ ions are reduced to form zinc atoms. The tin electrode is the anode, where tin atoms are oxidized to form Sn²⁺ ions.

The overall reaction occurs spontaneously, as the standard reduction potential for the reduction reaction is more positive than the standard reduction potential for the oxidation reaction. This means that the electrons will flow from the anode to the cathode, generating an electrical current.

The salt bridge is used to maintain charge neutrality in the two half-cells, as the electrons flow from the anode to the cathode, and ions must move to balance the charges. Na⁺ ions move towards the anode, while NO³⁻ ions move towards the cathode. This allows for the flow of ions to maintain charge neutrality in both half-cells.

As the reaction proceeds, the mass of the tin electrode will decrease as tin atoms are oxidized to form Sn²⁺ ions. Conversely, the mass of the zinc electrode will increase as zinc ions are reduced to form zinc atoms. This is due to the conservation of mass, as the total mass of the system remains constant.

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what is the sodium ion concentration in a solution prepared by mixing 0.345 mol na2so4 in enough water to make 2.90 l of solution?

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The sodium ion concentration in the solution is 0.238 M, calculated by dividing the total moles of Na+ (0.690 mol) by the solution volume (2.90 L).

To work out the sodium particle fixation in an answer ready by blending 0.345 mol Na2SO4 in enough water to make 2.90 L of arrangement, we can involve stoichiometry and the equation for molarity.

In the first place, we really want to decide the all out number of moles of sodium particles in the arrangement. Every mole of Na2SO4 separates into 2 moles of sodium particles, so we can work out the quantity of moles of sodium particles as follows:

0.345 mol Na2SO4 x (2 mol Na+/1 mol Na2SO4) = 0.690 mol Na+

Then, we can work out the grouping of sodium particles in the arrangement by isolating the quantity of moles of sodium particles by the volume of the arrangement in liters:

0.690 mol Na+/2.90 L = 0.238 M Na+

Accordingly, the sodium particle fixation in the arrangement is 0.238 M. This intends that for each liter of arrangement, there are 0.238 moles of sodium particles present. This estimation can be valuable in different synthetic applications, including deciding the ionic strength of an answer, working out response rates, and planning compound responses.

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unsaturated fatty acids have double bonds that are in the cis configuaration. what is the consequence

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The consequence of having cis configuration in double bonds of unsaturated fatty acids is that it creates a kink or bend in the fatty acid chain, which affects the packing of molecules and the fluidity of the membrane.

The cis configuration of double bonds in unsaturated fatty acids results in a kink or bend in the fatty acid chain. This bend affects the overall structure and function of the fatty acid. It causes the molecules to pack less tightly together, making them more fluid and flexible at room temperature. This property is important for cell membrane function, as it allows the membrane to remain fluid and adaptable to changing environmental conditions.

Additionally, the cis configuration can affect the biological activity of unsaturated fatty acids, influencing their interactions with enzymes and other molecules in the body.

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How many atoms of nitrogen are in 1.20 grams of aspartame?

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There are approximately 4.92 x 10^21 nitrogen atoms in 1.20 grams of aspartame.

What ingredients are in aspartame?

The two naturally occurring amino acids phenylalanine and aspartic acid, which are also parts of proteins in our bodies and food, are what makeup aspartame. Aspartame's sweet flavor comes from a small modification of the phenylalanine by the addition of a methyl group.

The molecular formula of aspartame is C14H18N2O5.

The molar mass of aspartame,

(14 x 12.01 g/mol) + (18 x 1.01 g/mol) + (2 x 14.01 g/mol) + (5 x 16.00 g/mol) = 294.30 g/mol

Aspartame's molecular weight in 1.20 grams can be computed as follows:

1.20 g / 294.30 g/mol = 0.00408 mol

Every aspartame molecule has two nitrogen atoms.

0.00408 mol x 2 = 0.00816 moles of nitrogen

So, we will use Avogadro's number in order to transform nitrogen moles to nitrogen atoms:

0.00816 mol x 6.022 x 10^23 atoms/mol = 4.92 x 10^21 atoms of nitrogen

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what is the selenide ion concentration for a .200m h2s solution that has the stepwise dissociation constant

Answers

To determine the selenide ion (Se2-) concentration for a 0.200 M H2S solution that has the stepwise dissociation constant, we need to use the equilibrium constants for the reaction of H2S with water and for the reaction of HSe- with water.

The stepwise dissociation of H2S in water can be represented as:

H2S + H2O ⇌ HS- + H3O+

K1 = [HS-][H3O+] / [H2S]

The stepwise dissociation of HSe- in water can be represented as:

HSe- + H2O ⇌ Se2- + H3O+

K2 = [Se2-][H3O+] / [HSe-]

We are given that the concentration of H2S is 0.200 M. At equilibrium, some of the H2S reacts with water to form HS- and H3O+. We can assume that the initial concentration of H2S is much greater than the concentrations of HS- and H3O+ formed, so we can approximate the concentration of H2S to be 0.200 M at equilibrium. We don't know the concentration of H3O+ at this point, so we will express it in terms of x.

H2S + H2O ⇌ HS- + H3O+

Initial concentration: 0.200M 0 0 0

Change: -x +x +x

Equilibrium concentration: 0.200-x x x -

Now we can use the equilibrium concentrations to calculate the values of K1 and K2 using the given stepwise dissociation constants:

K1 = 1.1 × 10^-7 = [HS-][H3O+] / [H2S]

K2 = 1.3 × 10^-13 = [Se2-][H3O+] / [HSe-]

We can express [HSe-] in terms of [HS-] and [H2S] using the acid dissociation constant expression for H2S:

K1 = [HS-][H3O+] / [H2S]

1.1 × 10^-7 = x^2 / (0.200 - x)

Solving for x, we get:

x = 5.5 × 10^-5 M

This is the concentration of [HS-] and [H3O+] at equilibrium. To find the concentration of [Se2-], we can use the equilibrium constant expression for the reaction of HSe- with water:

K2 = [Se2-][H3O+] / [HSe-]

1.3 × 10^-13 = [Se2-](5.5 × 10^-5) / (0.200 - 5.5 × 10^-5)

Solving for [Se2-], we get:

[Se2-] = 2.6 × 10^-14 M

Therefore, the selenide ion concentration for a 0.200 M H2S solution that has the stepwise dissociation constant is 2.6 × 10^-14 M.

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